Quarterly report on measurements of radionuclides in ground level air in Sweden



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FOI-R--0918--SE September 2003 ISSN 1650-1942 User report Catharina Söderström, Rune Arntsing, Peter Jansson, Karin Lindh, Ingemar Vintersved Quarterly report on measurements of radionuclides in ground level air in Sweden Second quarter 2003 Systems Technology SE-172 90 Stockholm

SWEDISH DEFENCE RESEARCH AGENCY Systems Technology SE-172 90 Stockholm FOI-R--0918--SE September 2003 ISSN 1650-1942 User report Catharina Söderström, Rune Arntsing, Peter Jansson, Karin Lindh, Ingemar Vintersved Quarterly report on measurements of radionuclides in ground level air in Sweden Second quarter 2003

Issuing organization Report number, ISRN Report type FOI Swedish Defence Research Agency FOI-R--0918--SE User report Systems Technology SE-172 90 Stockholm Author/s (editor/s) Catharina Söderström Rune Arntsing Peter Jansson Karin Lindh Ingemar Vintersved Report title Research area code 3. Protection against Weapons of Mass Destruction Month year September 2003 Customers code 2. NBC Defence Research Sub area code Project no. E6876 31 Nuclear Defence Research Project manager Katarina Wilhelmsen-Rolander Approved by Scientifically and technically responsible Quarterly report on measurements of radionuclides in ground level air in Sweden. Second quarter 2003. Abstract (not more than 200 words) Filtering of ground level air is performed weekly at seven different locations in Sweden: Kiruna, Umeå,, Ursvik, Grindsjön, Visby and Lgbyhed. The filters are compressed and the contents of different radionuclides are measured by gamma spectroscopy. Precipitation is also collected at four of the stations: Kiruna,, Ursvik and Lgbyhed, the samples are ashed and the contents of radionuclides measured. The levels of 7 Be and 137 Cs in air and deposition are presented for the different stations. Other anthropogenic radionuclides detected, if any, are also presented. Keywords Airborne radionuclides, deposition, 7 Be, 137 Cs, 82 Br Further bibliographic information Language English ISSN 1650-1942 Pages 8 p. Price acc. to pricelist Security classification 2

Utgivare Rapportnummer, ISRN Klassificering Totalförsvarets Forskningsinstitut - FOI FOI-R--0918--SE Användarrapport Systemteknik 172 90 Stockholm Författare/redaktör Catharina Söderström Rune Arntsing Peter Jansson Karin Lindh Ingemar Vintersved Rapportens titel (i översättning) Forskningsområde 3. Skydd mot massförstörelsevapen Månad, år September 2003 Verksamhetsgren 2. NBC-skyddsforskning Delområde 31 N-forskning Projektledare Radionuklider i markluft i Sverige. Kvartalsrapport, andra kvartalet 2003. Projektnummer E6876 Katarina Wilhelmsen-Rolander Godkänd av Tekniskt och/eller vetenskapligt ansvarig Sammanfattning (högst 200 ord) Stationer för filtrering av markluft finns på sju olika ställen i Sverige: Kiruna, Umeå,, Ursvik, Grindsjön, Visby och Lgbyhed. Filtren analyseras veckovis genom gammaspektroskopi med germaniumdetektor. Nederbörd samlas in på fyra av dessa stationer: Kiruna,, Ursvik och Lgbyhed. Nederbördsproven askas in och mäts på samma sätt. Halterna i luft och deposition av 7 Be och 137 Cs presenteras för de olika stationerna. I de fall andra antropogena radionuklider detekterats presenteras även dessa. FOI1004 Utgåva 05 2001.02 www.signon.se/foi Sign On AB Nyckelord Luftburen radioaktivitet, deposition, 7 Be, 137 Cs, 82 Br Övriga bibliografiska uppgifter Språk Engelska ISSN 1650-1942 Antal sidor: 8 s. Distribution enligt missiv Pris: Enligt prislista Sekretess 3

FOI-R--0918--SE Sampling and analysis procedures Sampling of ground level air is performed at seven different locations in Sweden, as follows: Kiruna Kiruna: 67,84 N 20,42 O Umeå: 63,85 N 20,34 O : 60,40 N 17,14 O Ursvik: 59,39 N 17,96 O Grindsjön: 59,07 N 17,82 O Visby: 57,63 N 18,32 O Lgbyhed: 56,08 N 13,23 O Umeå Ursvik Grindsjön Visby Lgbyhed At all stations except at Grindsjön, 1000 m 3 /h of air is filtered through a glass fibre filter (Camfil type CS 5.0). At Grindsjön 5500 m 3 /h of air is filtered through 5 filters. At each station the filters are changed twice a week (Monday and Thursday or Friday) and sent by mail to our laboratory for measurement and analysis. Weekly samples are made from each station by taking 3/4 of each filter (1/4 of the filter is left for the archive) and compress them together into a small disc (diameter 60 mm, thickness 13 mm). These samples are measured, 3-4 days after the collection, on well shielded High Purity Germanium (HPGe) detectors. From the Grindsjön station, the 10 filters produced per week are assembled in a Marinelli like geometry by pressing them into one circular disc, placed on top of the detector, and into five rectangular bricks (77 mm by 48 mm by 13 mm) placed around the detector. At four of the stations (Kiruna, Umeå, Ursvik and Lgbyhed) a small part of the air flow (12m 3 /h) that has passed the filter is taken through a charcoal cartridge in order to collect gaseous iodine. The cartridges are changed weekly but only analysed if particulate iodine in greater amount has been detected in the filter. The stations in Kiruna,, Ursvik and Lgbyhed are each equipped with a big stainless steel funnel (1m radius) to collect the precipitation that is passed through a cartridge consisting of a filter part, an anion part and a cation part. The cartridges are changed weekly and sent by mail to our laboratory. Four samples are combined to a monthly sample by ashing. The samples are measured on our HPGe detectors. From these measurements the total deposition is calculated. Radionuclides seen in the filters are normally only the naturally occurring radon daughters and 7 Be. Most of our stations also detect 137 Cs, which is due to the resuspension of the Chernobyl fallout. In tables I and II the concentrations of 7 Be and 137 Cs are presented. The depositions at the stations where we collect precipitation are presented in table III. Sometimes we also detect other anthropogenic radionuclides and in that case these are presented in Table IV. 4

Table I FOI-R--0918--SE 7 Be concentrations in Sweden, second quarter 2003 Week starting Kiruna Umeå Ursvik Grindsjön Visby Lgbyhed 31-mar 1210 (0.2) 1590 (0.2) 1850 (0.3) 1790 (0.3) 1890 (0.1) 1590 (0.3) 1920 (0.2) 7-2250 (0.1) 2240 (0.1) 1810 (7) (0.2) 1740 (0.3) 1840 (0.1) 1720 (0.2) 2120 (0.3) 14-3040 (1) (0.1) 2620 (1) (0.2) 3380 (8) (0.2) 3220 (11) (0.2) 3190 (0.1) 2890 (1) (0.1) 3650 (0.1) 21-1610 (2) (0.1) 1980 (2) (0.2) 2470 (2) (0.4) 2430 (12) (0.2) 3010 (0.1) 3230 (2) (0.2) 3390 (0.1) 28-2570 (0.2) 2150 (5) (0.2) 1380 (0.3) 1250 (0.2) 1490 (13) (0.1) 1380 (0.3) 1970 (0.2) 5-may 1650 (0.2) 2330 (6) (0.2) 2030 (0.2) 2190 (0.1) 2390 (14) (0.1) 2440 (0.2) 2690 (0.1) 12-may 2590 (0.2) 3040 (0.1) 2970 (0.2) 2740 (0.1) 2500 (0.1) 2320 (0.2) 2630 (0.2) 19-may 2480 (0.1) 1280 (0.2) 1910 (0.2) 2400 (0.2) 2260 (0.1) 2360 (0.2) 2030 (0.1) 26-may 1640 (0.2) 1720 (0.2) 2140 (0.3) 2350 (0.2) 2320 (0.1) 2550 (0.2) 2780 (0.1) 2-2120 (3) (0.1) 2240 (3) (0.1) 2730 (9) (0.1) 3250 (3) (0.1) 2990 (3) (0.1) 2560 (3) (0.2) 2690 (3) (0.1) 9-1550 (4) (0.2) 2270 (4) (0.2) 2290 (10) (0.3) 2350 (4) (0.1) 2550 (4) (0.1) 2400 (4) (0.2) 1870 (4) (0.2) 16-3180 (0.1) 2740 (0.1) 2420 (0.2) 3050 (0.1) 3130 (0.1) 2800 (0.1) 1560 (0.2) 23-3740 (0.1) 4160 (0.1) 3710 (0.1) 4460 (0.1) 4510 (0.1) 4150 (0.1) 3640 (0.1) Values are given in µbq/m 3. Error estimates (1σ %) are given in brackets. 1) Eight days filter, 14-22/4 2) Six days filter, 22-28/4 3) Eight days filter, 2-10/6 4) Six days filter, 10-16/6 5) Eight days filter, 28/4-6/5 6) Six days filter, 6 12/5 7) Eight days filter, 7 15/4 8) Seven days filter, 15 22/4 9) Nine days filter, 2 11/6 10) Five days filter, 11 16/6 11) Nine days filter, 14 23/4 12) Five days filter, 23 28/4 13) Nine days filter, 28/4 7/5 14) Five days filter, 7 12/5 5000 4000 3000 2000 1000 Kiruna Umeå Ursvik Grindsjön Visby Lgbyhed 0 31- mar 07-14- 21-28- 05-12- 19-26- 02-09- 16-23- 5

FOI-R--0918--SE Table II 137 Cs concentrations in Sweden, second quarter 2003 Week starting Kiruna Umeå Ursvik Grindsjön Visby Lgbyhed 31-mar 0.1 (30) 3.9 (2) 4.4 (5) 0.9 (11) 0.6 (5) 1.6 (7) 0.8 (8) 7-0.2 (22) 3.1 (2) 4.7 (7) (4) 1.2 (9) 0.8 (3) 1.9 (7) 1.4 (11) 14-0.4 (1) (10) 4.8 (1) (2) 6.3 (8) (3) 1.5 (11) (6) 1.0 (3) 1.5 (1) (4) 5.4 (2) 21-0.2 (2) (20) 2.4 (2) (3) 6.2 (2) (4) 1.3 (12) (9) 0.9 (4) 1.8 (2) (5) 4.9 (1) 28-0.2 (23) 2.4 (5) (3) 4.7 (4) 0.8 (8) 0.4 (13) (6) 0.5 (33) 0.4 (12) 5-may 0.2 (27) 3.4 (6) (2) 6.8 (3) 0.3 (12) 0.2 (14) (19) 0.5 (16) 0.5 (10) 12-may 0.5 (13) 5.5 (2) 10.0 (2) 0.6 (7) 0.3 (10) 0.4 (20) 0.6 (11) 19-may 0.2 (14) 5.7 (1) 4.9 (4) 0.7 (8) 0.4 (6) 1.3 (8) 0.6 (9) 26-may 0.1 (33) 7.8 (1) 5.7 (3) 0.9 (8) 0.5 (6) 1.2 (9) 0.5 (10) 2-0.3 (3) (13) 5.9 (3) (1) 7.9 (9) (1) 0.8 (3) (7) 0.7 (3) (4) 1.3 (3) (5) 0.4 (3) (12) 9- <0.1 (4) 3.6 (4) (2) 4.2 (10) (5) 0.6 (4) (9) 0.5 (4) (7) 0.5 (4) (11) 0.1 (4) (70) 16-0.9 (7) 15.9 (1) 6.2 (2) 0.9 (6) 0.7 (4) 0.8 (7) 0.2 (20) 23-0.5 (13) 8.3 (1) 5.2 (2) 1.1 (6) 0.8 (4) 0.9 (7) 0.5 (10) Values are given in µbq/m 3. Error estimates (1σ %) are given in brackets. 1) Eight days filter, 14-22/4 2) Six days filter, 22-28/4 3) Eight days filter, 2-10/6 4) Six days filter, 10-16/6 5) Eight days filter, 28/4-6/5 6) Six days filter, 6 12/5 7) Eight days filter, 7 15/4 8) Seven days filter, 15 22/4 9) Nine days filter, 2 11/6 10) Five days filter, 11 16/6 11) Nine days filter, 14 23/4 12) Five days filter, 23 28/4 13) Nine days filter, 28/4 7/5 14) Five days filter, 7 12/5 18 16 14 12 10 8 6 4 2 Kiruna Umeå Ursvik Grindsjön Visby Lgbyhed 0 31- mar 07-14- 21-28- 05-12- 19-26- 02-09- 16-23- 6

Table III FOI-R--0918--SE Deposition measurements, second quarter 2003 Kiruna Weeks Period 7 Be 137 Cs Precipitation (mm) 12-15 17/3-14/4 4600 (0.8) <5 10.6 16-19 14/4-12/5 8800 (0.8) 7 (33) 13.4 20-23 12/5-10/6 22600 (0.4) 9 (25) 36.7 Weeks Period 7 Be 137 Cs Precipitation (mm) 11-14 10/3-7/4 11400 (0.8) 65 (5) 14.6 15-18 7/4-5/5 33400 (0.3) 140 (3) 50.6 19-22 5/5-2/6 50300 (0.3) 240 (2) 38.8 23 26 2/6 30/6 159000 (0.1) 320 (2) 70.7 Ursvik Weeks Period 7 Be 137 Cs Precipitation (mm) 14-17 31/3-28/4 12500 (0.6) 11 (28) 25.5 18-21 28/4-26/5 16400 (0.4) 14 (20) 43.7 22-25 26/5-23/6 105600 (0.2) 45 (6) 55.7 Lgbyhed Weeks Period 7 Be 137 Cs Precipitation (mm) 13-16 24/3-21/4 10800 (0.6) 15 (14) 17.5 17-20 21/4-19/5 68400 (0.2) 28 (10) 65.3 21-24 19/5-16/6 88900 (0.2) 23 (14) 73.5 Values are given in mbq/m 2. Error estimates (1σ %) are given in brackets. 7

FOI-R--0918--SE Table IV Other anthropogenic radionuclides detected, second quarter 2003 Week starting Station Isotope Concentration 23- (1) 82 Br 16 (13) Values are given in µbq/m 3. Error estimates (1σ %) are given in brackets. (1) On June 25 the isotope 82 Br (T 1/2 =35h) was used for gas flow measurements at Korsnäs AB in. Short tracer pulses of 82 Br in the form of ethyl bromide were injected into a closed system, a total of 5.55 GBq of 82 Br was injected. After each injection the dosing apparatus is pressure stabilized and small amounts of ethyl bromide can be released into the air. 8