Development status for syngas from solid forest residues via entrained flow gasification

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1 Development status for syngas from solid forest residues via entrained flow gasification Magnus Marklund

2 My origin 2

3 A view on viable aspects for BtL processes 1. Scale of economy: Very large plants are favorable, conversion principles needs to be up-scalable. 2. Fuel cost: Processes that are less sensitive to impurities in low grade fuel will be most viable. 3. Future access to renewable carbon resources: High energy efficiency, high carbon utilization, and accessible hydrogen will be competitive. 4. Product flexibility: A system that can produce both electricity and liquid fuel will be advantageous. 5. Physical size of large commercial plants: Ability to operate at high pressure will be favorable. 3

4 General applications in gasification % energi % el, % värme % el, % värme % el

5 General principle entrained flow gasification (EFG) 5

6 Solid Bio-EFG in Sweden 2016 MEVA Energy/PiteEnergi 3 MW CHP (Operational) SP ETC PEBG syngas pilot 1 bar (Operational)

7 MEVA Energy/PiteEnergi development plant 3 MW Hortlax, Piteå. Cyclone Gasifier Multistage cleaning cyclone gas cooling RME scrubber WESP Cooperation on specially designed gas engines with supplier Cummins Power Generation Ltd., UK. 7

8 Pressurized Entrained flow Biomass Gasifier (PEBG) Owner: SP ETC, Piteå Contact: Fredrik Weiland 1.0 MW th (~200 kg/h), 10 bar, Oxygen blown Approx. 800 h of operation Daily operation (some long-term tests, 4 days) Wood, Peat, Bark, Forest residue, Lignin, Pyrolysis oil In-house (Design Construction Operation)

9 Solid Bio-EFG (BtL) in Europe 2016 WoodSpirit (planned) BioTFuel (planned) UPM Stracel (planned) Bioliq BTL (in operation) Pilot plants Commercial

10 NER 300 Europe: Solid Bio-EFG UPM Stracell* Frankrike. FT. Status okänt, 1 st Call AIOS BTL Finland. FT. Avbrutet. WoodSpirit Nederländerna. Metanol. Status okänd. Pyrogrot Billerud Sverige. Pyrolysolja. Avbrutet GoBiGas 2 Sverige. SNG. Fas 1 pågår, fas 2? 2 nd Call Fast pyrolysis Estland. Pyrolysolja. Status okänd CHP Biomass pyrolysis Lettland. Pyrolysolja. Status okänd E.ON Bio2G Sverige. SNG. Status? * A final decision on whether or not the UPM Stracel BtL facility will proceed is reportedly pending, due to ongoing uncertainty over the regulatory environment for advanced biofuels in Europe. (

11 BIOTFUEL, FRANCE UDHE Prenflo PDQ gasifier pilot planned to be installed at the Dunkirk refinery of Total at a cost in excess of 100 M in??? 11

12 From Solid Biomass to clean Syngas EFG Process Optimisation Criteria 1. MAXimize process availability 2. MINimize the fuel pre-treatment requirements 3. MAXimize CGE with respect to considered application 4. MINimize soot and tar formation in reactor 5. MAXimize particulate separation from product gas 12

13 PEBG: project history Start PFD Component Design Assembly Control System 1 st Heat up Pressurised O 2 gasification Process R&D Pressure increase April 2009 Nov 2009 February 2010 May 2010 December 2010 April 2011 October 2011 August 2012 January 2014

14 PEBG: Process Overview

15 PEBG: Process Characterization CO, H 2, CH 4, C 2 H 4, C 2 H 2 CO, H 2 Weiland et al. Influence of process parameters on the performance of an oxygen blown entrained flow biomass gasifier, Fuel, vol. 153, p , 2015.

16 PEBG: Extractive sampling from the reactor core Weiland et al. Extractive sampling of gas and particulates from the reactor core of an entrained flow biomass gasifier, submitted to Energy and Fuels, 2016.

17 PEBG: Formation of Particulates, Gasification Wiinikka et al., Combust. Flame 161 (2014) Weiland et al., Aerosol Sci. Technol. 48 (2014)

18 PEBG: Slagging ash

19 PEBG TRL sawdust to raw syngas Fas TRL Kännetecken för uppnådd nivå Exempel på den mognadsnivå som ska uppnås Införande 9 Produkten har introducerats på marknaden och Produkt används med framgång tekniken har visat sig fungera i verklig (verifierad produktanvändning) användning 8 Test- och demonstrationsfasen är avslutad till Det komplett system är validerat potentiella kunders belåtenhet. Tekniken har funnit sin slutliga form, prestanda är bekräftade. Pilot- och demonstratorprojekt Teknisk forskning Grundforskning 7 Demonstration i driftsmiljö 6 Demonstration i relevant miljö Teknisk validering i relevant miljö Teknisk validering i laboratoriemiljö Experimentella bevis på konceptets potential föreligger 2 Teknikkoncept formulerade 1 Grundläggande principer observerade Tekniken har visat sig fungera i tester med prototyp- eller demonstrationsfordon i verklig driftsmiljö. Överlämning till produktutveckling. Systemet eller ett större delsystem har testats under verklighetsliknande förhållanden (t ex på provbana). Komponenter eller delsystem har testats under verklighetsliknande förhållanden (t ex testrigg eller testfordon). Teknikens livskraft verifierad. Komponenter eller delsystem har testats. Konceptets relation till andra system (t ex i ett komplett fordon) har bestämts. Analytiska eller experimentella studier har genomförts. Karakteristiska drag hos tekniken är kända. Möjliga applikationer har identifierats. Grundläggande principer studeras. Förfinad förutsägelse av prestanda. Vetenskapliga resultat finns som tyder på en möjlig praktisk tillämpning. Prestanda kan uppskattas.

20 Exemple: Survey SIA gasification/pyrolysis

21 My summary for BtL from bio-efg: In general: High ambitions low level of action Big investment grants available via EU but not sufficient! SEA: In long-term, BtL via EFG is of interets for Sweden Favorable market conditions and strong consortia needed for demonstration and commercialisation! Swedish competence is internationally competivite but lack solid technology providers. Further technology push efforts needed in order to be ready when market and actor timing is right.

22 Tack för uppmärksamheten!

23 PEBG Publications Weiland, F., Wiinikka, H., Hedman, H., Wennebro, J., Pettersson, E., Gebart, R. Influence of process parameters on the performance of an oxygen blown entrained flow biomass gasifier. Fuel 153 (2015) Leijenhorst, E.J., Assink, D., van de Beld, L., Weiland, F., Wiinikka, H., Carlsson, P., Öhrman, O.G.W. Entrained Flow gasification of straw,- and woodderived pyrolysis oil in a pressurized oxygen blown gasifier. Biomass and Bioenergy 79 (2015) Carlsson, P., Ma, C., Molinder, R., Weiland, F., Wiinikka, H., Öhman, M., Öhrman, O. Slag formation during Oxygen Blown Entrained-Flow Gasification of Stem Wood. Energy & Fuels 28 (2014) Weiland, F., Nilsson, P., Wiinikka, H., Gudmundsson, A., Gebart, R., Sanati, M. Online characterization of syngas particulates using aerosol mass spectrometry in entrained-flow biomass gasification. Aerosol Science and Technology 48 (2014) Molinder, R., Öhrman, O.G.W. Characterization and cleanup of waste water from pressurized entrained flow biomass gasification. ACS Sustainable Chemistry & Engineering 2 (2014) Andersson, J., Lundgren, J., Marklund, M., Methanol production via pressurized entrained flow biomass gasification Techno-economic comparison of integrated vs. stand-alone production. Biomass and Bioenergy 64 (2014) Weiland, F., Nordwaeger, M., Olofsson, I., Wiinikka, H., Nordin, A. Entrained flow gasification of torrefied wood residues. Fuel Processing Technology 125 (2014)

24 PEBG Publications Öhrman, O.G.W., Molinder, R., Weiland, F., Johansson, A.C. Analysis of trace compounds generated by pressurized oxygen blown entrained flow biomass gasification. Environmental Progress & Sustainable Energy 33 (2014) Wiinikka, H., Weiland, F., Pettersson, E., Öhrman, O., Carlsson, P., Stjernberg, J. Characterisation of submicron particles produced during oxygen blown entrained flow gasification of biomass. Combustion and Flame 161 (2014) Ma, C., Weiland, F., Hedman, H., Boström, D., Backman, R., Öhman, M., Characterization of Reactor Ash Deposits from Pilot-Scale Pressurized Entrained-Flow Gasification of Woody Biomass. Energy & Fuels 27 (2013) Öhrman, O.G.W., Weiland, F., Pettersson, E., Johansson, A.C., Hedman, H., Pedersen, M. Pressurized Oxygen Blown Entrained Flow Gasification of a Biorefinery Lignin Residue. Fuel Processing Technology 115 (2013) Weiland, F., Hedman, H., Marklund, M., Wiinikka, H., Öhrman, O., Gebart, R. Pressurized oxygen blown entrained-flow gasification of wood powder. Energy & Fuels 27 (2013)