Europeiska unionens råd Bryssel den 26 juli 2017 (OR. en)

Transkript

1 Europeiska unionens råd Bryssel den 26 juli 2017 (OR. en) 11526/17 ADD 3 FÖLJENOT från: inkom den: 24 juli 2017 till: Europeiska kommissionen Rådets generalsekretariat Komm. dok. nr: - Annex (part 3) Ärende: COMPET 561 ENV 700 CHIMIE 71 MI 573 ENT 176 Bilaga (del 3) till KOMMISSIONENS FÖRORDNING (EU) / av den XXX om ändring, för anpassning till den tekniska och vetenskapliga utvecklingen, av Europaparlamentets och rådets förordning (EG) nr 1272/2008 om klassificering, märkning och förpackning av ämnen och blandningar För delegationerna bifogas dokument - Annex (part 3). Bilaga: - Annex (part 3) 11526/17 ADD 3 /ss DG G 3A SV

2 signalords N-acetyl-N-[5-cyano-3-(2- dibutylamino-4-fenyltiazol-5- ylmetylen)-4-metyl-2,6-dioxo- 1,2,3,6-tetrahydropyridin-1- yl]bensamid bensyl-2-metyl-3-butennitril acetamiprid (ISO); (E)-N 1 -[(6-klor-3-pyridyl)metyl]-N 2 - cyano-n 1 -metylacetamidin N-butyl-3-(2-klor-4- nitrofenylhydrazono)-1-cyano-2- metylprop-1-en-1,3-dikarboximid klorfenapyr (ISO); 4-brom-2-(4- klorfenyl)-1-etoximetyl-5- trifluormetylpyrrol-3-karbonitril M = (±)-α-[(2-acetyl-5- metylfenyl)amino]-2,6- diklorbensenacetonitril Aquatic Chronic 4 H413 H (2-{4-[2-(4- cyanofenyl)vinyl]fenyl}vinyl)benson itril Aquatic Chronic 4 H413 H X reaktionsblandning av: (E)-2,12- tridekadiennitril; (E)-3,12- tridekadiennitril; (Z)-3,12- tridekadiennitril

3 signalords ,2,4-trimetyl-4-fenylbutannitril fenylhexannitril ,4'-ditiobis(5-amino-1-(2,6-diklor- 4-(trifluormetyl)fenyl)-1H-pyrazol- 3-karbonitril) '-((2-butyl-4-oxo-1,3- diazaspiro[4.4]non-1-en-3- yl)metyl)(1,1'-bifenyl)-2-karbonitril (S)-2,2-difenyl-2-(3- pyrrolidinyl)acetonitrilhydrobromid (cis-3-hexenyloxi)propannitril cyklohexyliden-2-fenylacetonitril (4-klor-2-nitrofenylazo)-1,2- dihydro-6-hydroxi-1,4-dimetyl-2- oxopyridin-3-karbonitril Aquatic Chronic 4 H413 H piperidin-1-ylbensonitril

4 signalords X 1-(3-cyklopentyloxi-4-metoxifenyl)- 4-oxocyklohexankarbonitril H373** H373** (4-(4-(butyl-(1- metylhexyl)amino)fenyl)-3-cyano-5- oxo-1,5-dihydropyrrol-2- yliden)propandinitril reaktionsblandning av: 5-(2-cyano-4- nitrofenylazo)-2-(2-(2- hydroxietoxi)etylamino)-4-metyl-6- fenylaminonikotinonitril; 5-(2-cyano-4-nitrofenylazo)-6-(2-(2- hydroxietoxi)etylamino)-4-metyl-2- fenylaminonikotinonitril Aquatic Chronic 4 H413 H (R)-4-(4-dimetylamino-1-(4- fluorfenyl)-1-hydroxibutyl)-3- (hydroximetyl)bensonitril (S)-4-(4-dimetylamino-1-(4- fluorfenyl)-1-hydroxibutyl)-3- (hydroximetyl)bensonitril (R,S)-4-(4-dimetylamino-1-(4- fluorfenyl)-1-hydroxibutyl)-3- (hydroximetyl)bensonitril (R,S)-4-(4-dimetylamino-1-(4- fluorfenyl)-1-hydroxibutyl)-3- (hydroximetyl)bensonitrilhemisulfat

5 signalords N-metyl-Ncyanometylmorfoliniummetylsulfat (cyanometyl)-4-metylmorfolin-4- iumvätesulfat esfenvalerat (ISO); (S)-α-cyano-3-fenoxibensyl-(S)-2-(4- klorfenyl)-3-metylbutyrat M = X 5-amino-1-(2,6-diklor-4- (trifluormetyl)fenyl)-1h-pyrazol-3- karbonitril metyl-2-[(2-nitrofenyl)amino]-3- tiofenkarbonitril fluor-4-hydroxibensonitril (S)-α-hydroxi-3- fenoxibensenacetonitril

6 signalords cyanometyltrimetylammoniummetyl sulfat salter av bromoxinil, utom sådana som är upptagna på annat ställe i denna bilaga Repr. 2 Acute Tox. 2 * H361d *** H330 H361d *** H330 M = 10 A salter av ioxinil, utom sådana som är upptagna på annat ställe i denna bilaga Repr. 2 Eye Irrit. 2 H361d *** H361d *** M = 10 A nitropropan Flam. Liq. 3 H226 GHS02 H 226 * nitropropan Flam. Liq. 3 Carc. 1B H226 GHS02 H nitrobensen Carc. 2. Repr. 1B Acute Tox. 3 Acute Tox. 3 Acute Tox. 3 STOT RE 1 H360F H372 (blod) H360F H372 (blod) 368

7 signalords dinitrobensen; [1] 1,4-dinitrobensen; [2] 1,3-dinitrobensen; [3] 1,2-dinitrobensen [4] [1] [2] [3] [4] [1] [2] [3] [4] Acute Tox. 2 * Acute Tox. 1 Acute Tox. 2 * H330 H310 H300 H330 H310 H ,3,5-trinitrobensen Expl. 1.1 Acute Tox. 2 * Acute Tox. 1 Acute Tox. 2 * STOT RE 2 H201 H330 H310 H300 H373** GHS01 H201 H330 H310 H300 H373** nitrotoluen ,4-dinitrotoluen; [1] dinitrotoluen [2] [1] [2] [1] [2] Carc. 1B Muta. 2 Repr. 2 H341 H361f*** H373** H341 H361f*** H373** 369

8 signalords ,4,6-trinitrotoluen; TNT Expl. 1.1 H201 GHS01 H X 2,4,6-trinitrofenol; pikrinsyra Expl. 1.1 H201 GHS01 H salter av pikrinsyra Unst. Expl. H201 GHS01 H201 T ,4,6-trinitroanisol Expl. 1.1 H201 GHS01 H ,4,6-trinitro-m-kresol Expl. 1.1 H201 GHS01 H ,4,6-trinitro-m-xylen Expl. 1.1 H201 GHS01 H

9 signalords nitrofenol; p-nitrofenol dinitrofenol (reaktionsblandning av isomerer); [1] 2,4(eller 2,6)-dinitrofenol [2] [1] [2] [1] [2] ,4,6-trinitroresorcinol; styfninsyra Expl. 1.1 H201 GHS01 H bly-2,4,6-trinitro-m-fenylendioxid; bly- 2,4,6-trinitroresorcinoxid; blystyfnat Unst. Expl. Repr. 1A H200 H360Df GHS01 H200 H360Df bly-2,4,6-trinitro-m-fenylendioxid; bly-2,4,6-trinitroresorcinoxid; blystyfnat ( 20 % flegmatiseringsmedel) Expl. 1.1 Repr. 1A H201 H360Df GHS01 H201 H360Df 1 371

10 signalords X DNOC (ISO); 4,6-dinitro-o-kresol Muta. 2 Acute Tox. 2 * Acute Tox. 1 Acute Tox. 2 * Skin Irrit. 2 H341 H330 H310 H300 H341 H330 H310 H300 EUH natriumsalt av DNOC; natrium-4,6-dinitro-o-kresolat; [1] kaliumsalt av DNOC; kalium-4,6- dinitro-o-kresolat [2] [1] -[2] [1] [2] ammoniumsalt av DNOC; ammonium-4,6-dinitro-o-tolyloxid Acute Tox. 2 * Acute Tox. 1 Acute Tox. 2 * H330 H310 H300 H330 H310 H dinokap (ISO); (RS)-2,6-dinitro-4- oktylfenylkrotonater och (RS)-2,4- dinitro-6-oktylfenylkrotonater i vilka oktyl är en reaktionsblandning av 1-metylheptyl-, 1-etylhexyl- och 1- propylpentylgrupper Repr. 1B Skin Irrit. 2 H360D*** H373** H360D*** H373** M =

11 signalords binapakryl (ISO); 2-sek-butyl-4,6-dinitrofenyl-3- metylkrotonat Repr. 1B H360D *** H360D *** dinoseb (ISO); 6-sek-butyl-2,4-dinitrofenol Repr. 1B Eye Irrit. 2 H360Df H360Df EUH salter och estrar av dinoseb, utom sådana som är upptagna på annat ställe i denna bilaga Repr. 1B Eye Irrit. 2 H360Df H360Df EUH044 A dinokton; reaktionsblandning av isomerer: metyl-2-oktyl-4,6- dinitrofenylkarbonat, metyl-4-oktyl- 2,6-dinitrofenylkarbonat dinex (ISO); 2-cyklohexyl-4,6-dinitrofenol

12 signalords salter och estrar av dinex A dinoterb (ISO); 2-tert-butyl-4,6-dinitrofenol Repr. 1B Acute Tox. 2 * H360D *** H300 H360D *** H300 EUH X salter och estrar av dinoterb Repr. 1B Acute Tox. 2 * H360D *** H300 H360D *** H300 A bromfenoxim (ISO); 3,5-dibrom-4-hydroxibensaldehyd- O-(2,4-dinitrofenyl)oxim dinosam (ISO); 2-(1-metylbutyl)-4,6-dinitrofenol salter och estrar av dinosam A 374

13 signalords nitroetan Flam. Liq. 3 H226 GHS02 H226 * nitrometan Flam. Liq. 3 H226 GHS02 H226 * nitroacenaften Carc. 1B nitronaftalen Carc. 1B nitrobifenyl Carc. 1B nitrofen (ISO); 2,4-diklorfenyl-4-nitrofenyleter Carc. 1B Repr. 1B H360D *** H360D *** ,4-dinitrofenol X pendimetalin (ISO); N-(1-etylpropyl)-2,6-dinitro-3,4- xylidin

14 signalords kvintozen (ISO); pentaklornitrobensen teknazen (ISO); 1,2,4,5-tetraklor-3-nitrobensen reaktionsblandning av: 4,6-dinitro-2- (3-oktyl)fenylmetylkarbonat och 4,6- dinitro-2-(4- oktyl)fenylmetylkarbonat; dinokton trifluralin (ISO) (innehållande < 0,5 ppm NPDA); α, α, α-trifluor-2,6-dinitro-n,ndipropyl-p-toluidin (innehållande < 0,5 ppm NPDA); 2,6-dinitro-N,N-dipropyl-4- trifluormetylanilin (innehållande < 0,5 ppm NPDA); N,N-dipropyl-2,6-dinitro-4- trifluormetylanilin (innehållande < 0,5 ppm NPDA) Carc. 2 M = nitroanisol Carc. 1B natrium-3-nitrobensensulfonat Eye Irrit

15 signalords ,6-dinitrotoluen Carc. 1B Muta. 2 Repr. 2 H341 H361f *** H341 H361f *** ,3-dinitrotoluen Carc. 1B Muta. 2 Repr. 2 H341 H361f *** H341 H361f *** ,4-dinitrotoluen Carc. 1B Muta. 2 Repr. 2 H341 H361f *** H341 H361f *** ,5-dinitrotoluen Carc. 1B Muta. 2 Repr. 2 H341 H361f *** H341 H361f *** 377

16 signalords X hydrazintrinitrometan Expl. 1.1 **** Self-react. A Carc. 1B H201 H240 GHS01 H201 H ,3-dinitrofenol; [1] 2,5-dinitrofenol; [2] 2,6-dinitrofenol; [3] 3,4-dinitrofenol; [4] salter av dinitrofenol [5] [1] [2] [3] [4]-[5] [1] [2] [3] [4]-[5] ,5-dinitrotoluen Carc. 1B Muta. 2 Repr. 2 H341 H361f *** H341 H361f *** ,2-dibrom-2-nitroetanol Expl. 1.1 Carc. 2 Skin Corr. 1A H201 GHS01 H201 * STOT SE 3; H335: C 1 % T klor-2,4-difluornitrobensen Skin Corr. 1B 378

17 signalords nitro-2-fenyl-1,3-propandiol STOT RE 1 H372 ** H372 ** EUH klor-6-(etylamino)-4-nitrofenol [(3-hydroxipropyl)amino]-3- nitrofenol Skin Irrit (E,Z)-4-klorfenyl(cyklopropyl)keton- O-(4-nitrofenylmetyl)oxim brom-2-nitropropanol Skin Corr. 1B [(4-klor-2-nitrofenyl)amino]etanol X mesotrion (ISO); 2-[4-(metylsulfonyl)-2- nitrobensoyl]-1,3-cyklohexandion

18 signalords nitrotoluen Carc. 1B Muta. 1B Repr. 2 H340 H361f *** H340 H361f *** litiumnatrium-3-amino-10-{4-(10- amino-6,13-diklor-4,11- disulfonatobenso[5,6][1,4]oxazino[2, 3-b]fenoxazin-3-ylamino)-6- [metyl(2-sulfonato-etyl)amino]- 1,3,5-triazin-2-ylamino}-6,13- diklorbenso[5,6][1,4]oxazino[2,3- b]fenoxazin-4,11-disulfonat STOT SE 2 ** H371 ** H371 ** natrium- och kalium-4-(3- aminopropylamino)-2,6-bis[3(4- metoxi-2-sulfofenylazo)-4-hydroxi- 2-sulfo-7-naftylamino]-1,3,5-triazin myskxylen; 5-tert-butyl-2,4,6-trinitro-m-xylen Expl. 1.1 Carc. 2 H201 GHS01 H201 T myskketon; 3,5-dinitro-2,6-dimetyl-4-tertbutylacetofenon; 4'-tert-butyl-2', 6'-dimetyl-3', 5'-dinitroacetofenon Carc ,4-diklor-2-(1,1,2,3,3,3- hexafluorpropoxi)-5-nitrobensen

19 signalords reaktionsblandning av: 2- metylsulfanyl-4,6-bis-(2-hydroxi-4- metoxi-fenyl)-1,3,5-triazin; 2-(4,6-bis-metylsulfanyl-1,3,5- triazin-2-yl)-5-metoxifenol mesyl-2-nitrotoluen Repr. 2 H361f*** H361f*** litiumkaliumnatrium-n,n''-bis{6-[7- [4-(4-klor-1,3,5-triazin-2-yl)amino- 4-(2-ureidofenylazo)]naftalen-1,3,6- trisulfonato}-n'-(2- aminoetyl)piperazin triklornitrometan; klorpikrin Acute Tox. 2 * Eye Irrit. 2 STOT SE 3 Skin Irrit. 2 H330 H335 H330 H ,1-diklor-1-nitroetan klordinitrobensen C 381

20 signalords X 2-klor-1,3,5-trinitrobensen Expl. 1.1 Acute Tox. 2 * Acute Tox. 1 Acute Tox. 2 * H201 H330 H310 H300 GHS01 H201 H330 H310 H klor-4-nitrobensen Carc. 2 Muta. 2 H341 H klornitroaniliner, utom sådana som är upptagna på annat ställe i denna bilaga Acute Tox. 2 * Acute Tox. 1 Acute Tox. 2 * H330 H310 H300 H330 H310 H300 A C klor-1-nitropropan * ,6-diklor-4-nitroanisol klor-4-nitroanilin

21 signalords brom-1-(2-furyl)-2-nitroetylen Skin Corr. 1B azobensen Carc. 1B Muta. 2 H341 H azoxibensen fenaminosulf (ISO); natrium-4- dimetylaminobensendiazosulfonat metyl-onn-azoximetylacetat; metylazoximetylacetat Carc. 1B Repr. 1B H360D *** H360D *** dinatrium{5-[(4'-((2,6-hydroxi-3-((2- hydroxi-5- sulfofenyl)azo)fenyl)azo)(1,1'- bifenyl)-4-yl)azo]salicylato(4- )}kuprat(2-); CI Direct Brown Carc. 1B o-tolylazo-o-toluidin; 4-amino-2',3-dimetylazobensen; fast garnet GBC base; AAT; o-aminoazotoluen Carc. 1B 383

22 signalords tricyklazol (ISO); 5-metyl-1,2,4-triazolo(3,4-b)benso- 1,3-tiazol; aminoazobensen; 4-fenylazoanilin Carc. 1B X natrium(1-(5-(4-(4-anilino-3- sulfofenylazo)-2-metyl-5- metylsulfonamidofenylazo)-4- hydroxi-2-oxido-3- (fenylazo)fenylazo)-5-nitro-4- sulfonato-2-naftolato)järn(ii) '-(2-cyano-4,6-dinitrofenylazo)-5'- (N,N-dipropylamino)propionanilid N,N,N',N'-tetrametyl-3,3'- (propylenbis(iminokarbonyl-4,1- fenylenazo(1,6-dihydro-2-hydroxi-4- metyl-6-oxopyridin-3,1- diyl)))di(propylammonium)dilaktat

23 signalords reaktionsblandning av 2,2- iminodietanol-6-metyl-2-(4-(2,4,6- triaminopyrimidin-5- ylazo)fenyl)bensotiazol-7-sulfonat och 2-metylaminoetanol-6-metyl-2- (4-(2,4,6-triaminopyrimidin-5- ylazo)fenyl)bensotiazol-7-sulfonat och N,N-dietylpropan-1,3-diamin-6- metyl-2-(4-(2,4,6-triaminopyrimidin- 5-ylazo)fenyl)bensotiazol-7-sulfonat trilitium-1-hydroxi-7-(3- sulfonatoanilino)-2-(3-metyl-4-(2- metoxi-4-(3- sulfonatofenylazo)fenylazo)fenylazo )naftalen-3-sulfonat Expl. 1.3 **** H203 GHS01 H (tetranatrium-1-(4-(3-acetamido-4- (4'-nitro-2,2'-disulfonatostilben-4- ylazo)anilino)-6-(2,5- disulfonatoanilino)-1,3,5-triazin-2- yl)-3-karboxipyridinium)hydroxid tetranatrium-4-amino-5-hydroxi-6- (4-(2-(2- (sulfonatooxi)etylsulfonyl)etylkarba moyl)fenylazo)-3-(4-(2- (sulfonatooxi)etylsulfonyl)fenylazo) naftalen-2,7-disulfonat

24 signalords reaktionsblandning av 1,1'- ((dihydroxifenylen)bis(azo-3,1- fenylenazo(1-(3- dimetylaminopropyl)-1,2-dihydro-6- hydroxi-4-metyl-2-oxopyridin-5,3- diyl)))dipyridiniumdikloriddihydrokl orid, blandade isomerer och 1-(1-(3- dimetylaminopropyl)-5-(3-((4-(1-(3- dimetylaminopropyl)-1,6-dihydro-2- hydroxi-4-metyl-6-oxo-5-pyridinio- 3-pyridylazo)fenylazo)-2,4(eller 2,6 eller 3,5)- dihydroxifenylazo)fenylazo)-1,2- dihydro-6-hydroxi-4-metyl-2-oxo-3- pyridyl)pyridiniumdiklorid (4- (dietylaminopropylkarbamoyl)fenyla zo)-3-oxo-n-(2,3-dihydro-2- oxobensimidazol-5-yl)butyramid tetraammonium-5-(4-(7-amino-1- hydroxi-3-sulfonato-2-naftylazo)-6- sulfonato-1-naftylazo)isoftalat tetralitium-6-amino-4-hydroxi-3-(7- sulfonato-4-(4-sulfonatofenylazo)-1- naftylazo)naftalen-2,7-disulfonat X tetrakis(tetrametylammonium) 6-amino-4-hydroxi-3-(7-sulfonato-4- (4-sulfonatofenylazo)-1- naftylazo)naftalen-2,7-disulfonat

25 signalords (4-(4-cyano-3-metylisotiazol-5- ylazo)-n-etyl-3- metylanilino)etylacetat Skin Irrit. 2 Aquatic Chronic 4 H413 H dimetylaminobensendiazonium-3- karboxi-4-hydroxibensensulfonat Self-react. C H242 GHS02 H242 T dinatrium-7-(4,6-diklor-1,3,5-triazin- 2-ylamino)-4-hydroxi-3-(4-(2- (sulfonatooxi)etylsulfonyl)fenylazo) naftalen-2-sulfonat bensidinbaserade azofärgämnen; 4,4'-diarylazobifenyl-färgämnen, utom sådana som är upptagna på annat ställe i denna bilaga Carc. 1B A dinatrium-4-amino-3-[[4'-[(2,4- diaminofenyl)azo][1,1'-bifenyl]-4- yl]azo]-5-hydroxi-6- (fenylazo)naftalen-2,7-disulfonat; C.I. Direct Black Carc. 1B Repr. 2 H361d *** H361d *** tetranatrium-3,3'-[[1,1'-bifenyl]-4,4'- diylbis(azo)]bis[5-amino-4- hydroxinaftalen-2,7-disulfonat]; C.I. Direct Blue Carc. 1B Repr. 2 H361d *** H361d *** 387

26 signalords dinatrium-3,3'-[[1,1'-bifenyl]-4,4'- diylbis(azo)]bis(4-aminonaftalen-1- sulfonat); C.I. Direct Red Carc. 1B Repr. 2 H361d *** H361d *** C,C'-azodi(formamid) Resp. Sens. 1 H334 H334 G o-dianisidinbaserade azofärgämnen; 4,4'-diarylazo-3,3'- dimetoxibifenylfärgämnen, utom sådana som är upptagna på annat ställe i denna bilaga Carc. 1B A o-tolidinbaserade färgämnen; 4,4'-diarylazo-3,3'- dimetylbifenylfärgämnen, utom sådana som är upptagna på annat ställe i denna bilaga Carc. 1B A X 4,4'-(4-iminocyklohexa-2,5- dienylidenmetylen)dianilinhydroklor id; C.I. Basic Red Carc. 1B ,4,5,8-tetraaminoantra kinon; C.I. Disperse Blue Carc. 1B Skin Irrit

27 signalords hexanatrium[4,4''-azoxibis(2,2'- disulfonatostilben-4,4'diylazo)]- bis[5'-sulfonatobensen-2,2'-diolato- O(2), O(2), N(1)]-koppar(II) N-(5-(bis(2-metoxietyl)amino)-2-((5- nitro-2,1-bensisotiazol-3- yl)azo)fenylacetamid Aquatic Chronic 4 H413 H tetralitium-6-amino-4-hydroxi-3-[7- sulfonato-4-(5-sulfonato-2- naftylazo)-1-naftylazo]naftalen-2,7- disulfonat (4-(5,6(eller 6,7)-diklor-1,3- bensotiazol-2-ylazo)-n-metyl-mtoluidino)etylacetat (eller 5)-(4-(N-bensyl-N- etylamino)-2-metylfenylazo)-1,4- dimetyl-1,2,4-triazoliummetylsulfat trinatrium-1-hydroxinaftalen-2-azo- 4'(5',5''-dimetylbifenyl)-4''-azo(4''- fenylsulfonyloxibensen)-2',2'',4- trisulfonat Eye Irrit [((4,6-diklor-1,3,5-triazin-2- yl)amino)-4-hydroxi-3-(4-((2- sulfoxi)etyl)sulfonyl)fenylazo]naftal en-2-sulfonsyra

28 signalords (5-acetylamino-4-(4-[4,6-bis(3- dietylaminopropylamino)-1,3,5- triazin-2-ylamino]fenylazo)-2-(2- metoxietoxi)fenylazo)-6-amino-4- hydroxi-2-naftalensulfonsyra [[4[[4,6-bis[[3- (dietylamino)propyl]amino]-1,3,5- triazin-2-yl]amino]fenyl]azo]-n- (2,3-dihydro-2-oxo-1Hbensimidazol-5-yl)-3-oxobutanamid X trinatrium-5-amino-3-[5-(2- bromakryloylamino)-2- sulfonatofenylazo]-4-hydroxi-6-(4- vinylsulfonylfenylazo)naftalen-2,7- disulfonat

29 signalords reaktionsblandning av: trinatrium- N(1')-N(2):N(1''')-N(2'')-η-6-[2- amino-4-(eller 6)-hydroxi-(eller 4- amino-2-hydroxi)fenylazo]-6''-(1- karbaniloyl-2-hydroxiprop-1- enylazo)-5',5'''-disulfamoyl-3,3''- disulfonatobis(naftalen-2,1'- azobensen-1,2'-diolato-o(1), O(2'))- kromat; trinatrium-n(1')-n(2):n(1''')n(2'')-η- 6,6''-bis(1-karbaniloyl-2- hydroxiprop-1-enylazo)-5',5'''- disulfamoyl-3,3''-disulfonato bis(naftalen-2,1'-azobensen-1,2'- diolato-o(1),o(2'))-kromat; trinatrium-n(1')-n(2):n(1''')n(2'')-η- 6,6''-bis[2-amino-4-(eller 6)-hydroxi- (eller 4-amino-2-hydroxi)fenylazo]- 5',5'''-disulfamoyl-3,3''- disulfonatobis(naftalen-2,1'- azobensen-1,2'-diolato-o(1),o(2'))- kromat (2:1:1)

30 signalords reaktionsblandning av: tertalkyl(c 12 -C 14 )ammoniumbis[1-[(2- hydroxi-5-nitrofenyl)azo]-2- naftalenolato(2-)]-kromat(1-); tertalkyl(c 12 -C 14 )ammoniumbis[1-[(2- hydroxi-4-nitrofenyl)azo]-2- naftalenolato(2)]-kromat(1-); tertalkyl(c 12 -C 14 )ammoniumbis[1-[[5- (1,1-dimetylpropyl)-2-hydroxi-3- nitrofenyl]azo]-2-naftalenolato(2-)]- kromat(1-); tert-alkyl(c 12 - C 14 )ammonium [[1-[(2-hydroxi-5- nitrofenyl)azo]-2-naftalenolato(2)]- [1-[(2-hydroxi-5-nitrofenyl)azo]-2- naftalenolato(2)]]-kromat(1-); tert-alkyl(c 12 -C 14 )ammonium [[1- [[5-(1,1-dimetylpropyl)-2-hydroxi-3- nitrofenyl]azo]-2-naftalenolato(2-)]- [1-[(2-hydroxi-5-nitrofenyl)azo]-2- naftalenolato(2-)]]-kromat(1-); tertalkyl(c 12-C 14)ammonium ((1-(4(eller 5)-nitro-2- oxidofenylazo)-2-naftolato)(1-(3- nitro-2-oxido-5-pentylfenylazo)-2- naftolato))kromat(1-) [4-[N-(4-acetoxibutyl)-N- etyl]amino-2-metylfenylazo]-3- acetyl-5-nitrotiofen Aquatic Chronic 4 H413 H ,4'-diamino-2-metylazobensen

31 signalords reaktionsblandning av: 2-[[4-[N-etyl- N-(2-acetoxietyl)amino]fenyl]azo]- 5,6-diklorbensotiazol; 2-[[4-[N-etyl- N-(2-acetoxietyl)amino]fenyl]azo]- 6,7-diklorbensotiazol (1:1) Aquatic Chronic 4 H413 H reaktionsblandning av: 2-[[4-[bis(2- acetoxietyl)amino]fenyl]azo]-5,6- diklorbensotiazol; 2-[[4-[bis(2- acetoxietyl)amino]fenyl]azo]-6,7- diklorbensotiazol (1:1) Aquatic Chronic 4 H413 H reaktionsblandning av 7-[4-(3- dietylaminopropylamino)-6-(3- dietylammoniopropylamino)-1,3,5- triazin-2-ylamino]-4-hydroxi-3-(4- fenylazofenylazo)-naftalen-2- sulfonat, ättiksyra, mjölksyra (2:1:1)

32 signalords reaktionsblandning av: pentanatrium- 7-amino-3-[[4-[[4-[[4-[[4-[(6-amino- 1-hydroxi-3-sulfonato-2-naftyl]azo]- 7-sulfonato-1- naftyl]azo]fenyl]amino]-3- sulfonatofenyl]azo]-6-sulfonato-1- naftyl]azo]-4-hydroxinaftalen-2- sulfonat; pentanatrium-7-amino-8-[4-[4-[4-[4- (2-amino-5-hydroxi-7-sulfonato- naftalen-1-ylazo)-7- sulfonatonaftalen-1-ylazo]- fenylamino]-3-sulfonato-fenylazo]- 6-sulfonato-naftalen-1-ylazo]-4- hydroxi-naftalen-2-sulfonat; pentanatrium-3-amino-8-[4-[4-[4-[4- (6-amino-1-hydroxi-7-sulfonato- naftalen-1-ylazo)-7- sulfonatonaftalen-1-ylazo]- fenylamino]-3-sulfonato-fenylazo]- 6-sulfonato-naftalen-1-ylazo]-4- hydroxi-naftalen-2-sulfonat; tetranatrium-7-amino-4-hydroxi-3- [4-[4-[4-(4-hydroxi-7-sulfonatonaftalen-1-ylazo)-2-sulfonatofenylamino]fenylazo]-6- sulfonatonaftalen-1-ylazo]naftalen-2- sulfonat; tetranatrium-7-amino-4-hydroxi-3- [4-[4-[4-(4-amino-7-sulfonato- naftalen-1-ylazo)-2- sulfonatofenylamino]fenylazo]-6- sulfonato-naftalen-1-ylazo]naftalen- 2-sulfonat 394

33 signalords (4-(N-etyl-N-(2- hydroxi)etyl)amino-2- metylfenyl)azo-6-metoxi-3-metylbensotiazoliumklorid mononatriumaqua-[5-[[2,4- dihydroxi-5-[(2-hydroxi-3,5- dinitrofenyl)azo]fenyl]azo]-2- naftalensulfonat], järnkomplex X 2,2'-azobis[2- metylpropionamidin]dihydroklorid C.I. Disperse Yellow 3; N-[4-[(2-hydroxi-5- metylfenyl)azo]fenyl]acetamid Carc C.I. Solvent Yellow 14; 1-fenylazo-2-naftol Carc. 2 Muta. 2 Aquatic Chronic 4 H341 H413 H341 H hydroxi-1-(3-isopropoxipropyl)-4- metyl-2-oxo-5-[4- (fenylazo)fenylazo]-1,2-dihydro-3- pyridinkarbonitril Carc. 1B Aquatic Chronic 4 H413 H (6-(4-hydroxi-3-(2-metoxifenylazo)- 2-sulfonato-7-naftylamino)-1,3,5- triazin-2,4-diyl)bis[(amino-1- metyletyl)ammonium]formiat Carc. 1B 395

34 signalords oktanatrium-2-(6-(4-klor-6-(3-(n- metyl-n-(4-klor-6-(3,5-disulfonato- 2-naftylazo)-1-hydroxi-6- naftylamino)-1,3,5-triazin-2- yl)aminometyl)fenylamino)-1,3,5- triazin-2-ylamino)-3,5-disulfonato-1- hydroxi-2-naftylazo)naftalen-1,5- disulfonat reaktionsblandning av: natrium-5-[8- [4-[4-[4-[7-(3,5- dikarboxylatofenylazo)-8-hydroxi- 3,6-disulfonatonaftalen-1-ylamino]- 6-hydroxi-1,3,5-triazin-2-yl]-2,5- dimetylpiperazin-1-yl]-6-hydroxi- 1,3,5-triazin-2-ylamino]-1-hydroxi- 3,6-disulfonatonaftalen-2- ylazo]isoftalat; ammonium-5-[8-[4-[4-[4-[7-(3,5- dikarboxylatofenylazo)-8-hydroxi- 3,6-disulfonatonaftalen-1-ylamino]- 6-hydroxi-1,3,5-triazin-2-yl]-2,5- dimetylpiperazin-1-yl]-6-hydroxi- 1,3,5-triazin-2-ylamino]-1-hydroxi- 3,6-disulfonatonaftalen-2-ylazo]- isoftalat; 5-[8-[4-[4-[4-[7-(3,5- dikarboxylatofenylazo)-8-hydroxi- 3,6-disulfonatonaftalen-1-ylamino]- 6-hydroxi-1,3,5-triazin-2-yl]-2,5- dimetylpiperazin-1-yl]-6-hydroxi- 1,3,5-triazin-2-ylamino]-1-hydroxi- 3,6-disulfonaftalen-2-ylazo]- isoftalsyra

35 signalords dinatrium-5-[5-[4-(5-klor-2,6- difluorpyrimidin-4- ylamino)bensamido]-2- sulfonatofenylazo]-1-etyl-6-hydroxi- 4-metyl-2-oxo-3- pyridylmetylsulfonat oktanatrium-2-(8-(4-klor-6-(3-((4- klor-6-(3,6-disulfonato-2-(1,5- disulfonatonaftalen-2-ylazo)-1- hydroxinaftalen-8-ylamino)-1,3,5- triazin-2- yl)aminometyl)fenylamino)-1,3,5- triazin-2-ylamino)-3,6-disulfonato-1- hydroxinaftalen-2-ylazo)naftalen- 1,5-disulfonat Skin Irrit trinatrium-[4'-(8-acetylamino-3,6- disulfonato-2-naftylazo)-4''-(6- bensoylamino-3-sulfonato-2- naftylazo)-bifenyl-1,3',3'',1'''- tetraolato-o,o',o'',o''']koppar(ii) Carc. 1B X 4-(3,4-diklorfenylazo)-2,6-di-sekbutylfenol Skin Irrit (4-nitrofenylazo)-2,6-di-sekbutylfenol Eye Irrit. 2 Skin Irrit

36 signalords tetranatrium-5-[4-klor-6-(n-etyl- anilino)-1,3,5-triazin-2-ylamino]-4- hydroxi-3-(1,5-disulfonatonaftalen- 2-ylazo)-naftalen-2,7-disulfonat reaktionsblandning av: bis(tris(2-(2- hydroxi(1- metyl)etoxi)etyl)ammonium)-7- anilino-4-hydroxi-3-(2-metoxi-5- metyl-4-(4- sulfonatofenylazo)fenylazo)naftalen- 2-sulfonat; bis(tris(2-(2-hydroxi(2- metyl)etoxi)etyl)ammonium)-7- anilino-4-hydroxi-3-(2-metoxi-5- metyl-4-(4- sulfonatofenylazo)fenylazo)naftalen- 2-sulfonat tetranatrium-4-amino-3,6-bis(5-[4- klor-6-(2-hydroxietylamino)-1,3,5- triazin-2-ylamino]-2- sulfonatofenylazo)-5- hydroxinaftalen-2,7-disulfonat N,N-di-[poly(oxietylen)-co- poly(oxipropylen)]-4-[(3,5-dicyano- 4-metyl-2-tienyl)azo)]-3-metylanilin

37 signalords reaktionsblandning av: dinatrium(6- (4-anisidino)-3-sulfonato-2-(3,5- dinitro-2-oxidofenylazo)-1- naftolato)(1-(5-klor-2- oxidofenylazo)-2- naftolato)kromat(1-); trinatriumbis(5-(4-anisidino)-3- sulfonato-2-(3,5-dinitro-2- oxidofenylazo) tris(tetrametylammonium)-5- hydroxi-1-(4-sulfonatofenyl)-4-(4- sulfonatofenylazo)pyrazol-3- karboxylat ,4-bis[2,2'-[2-(N,Ndimetylamino)etyloxikarbonyl]fenyl azo]-1,3-dihydroxibensen, dihydroklorid dimetyl-3,3'-(n-(4-(4-brom-2,6- dicyanofenylazo)-3- hydroxifenyl)imino)dipropionat Aquatic Chronic 4 H413 H reaktionsblandning av: natrium/kalium(3-(4-(5-(5-klor-2,6- difluorpyrimidin-4-ylamino)-2- metoxi-3-sulfonatofenylazo)-2- oxidofenylazo)-2,5,7-trisulfonato-4- naftolato)koppar(ii); natrium/kalium(3-(4-(5-(5-klor-4,6- difluorpyrimidin-2-ylamino)-2- metoxi-3-sulfonatofenylazo)-2- oxidofenylazo)-2,5,7-trisulfonato-4- naftolato)koppar(ii)

38 signalords X reaktionsblandning av: tris(3,5,5- trimetylhexylammonium)-4-amino- 3-(4-(4-(2-amino-4- hydroxifenylazo)anilino)-3- sulfonatofenylazo)-5,6-dihydro-5- oxo-6-fenylhydrazononaftalen-2,7- disulfonat; tris(3,5,5-trimetylhexylammonium)- 4-amino-3-(4-(4-(4-amino-2- hydroxifenylazo)anilino)-3- sulfonatofenylazo)-5,6-dihydro-5- oxo-6-fenylhydrazononaftalen-2,7- disulfonat (2:1) (2,6-diklor-4-nitrofenylazo)-1- metyl-2-fenylindol dilitiumdinatrium(5,5'-diamino-(μ- 4,4'-dihydroxi-1:2κ-2,O4,O4',-3,3'- [3,3'-dihydroxi-1:2-κ-2-O3,O3'- bifenyl-4,4'-ylenbisazo-1:2-(n3, N4- η:n3',n4'-η)]-dinaftalen-2,7- disulfonato(8)))dikuprat(2-) (2,2'-(3,3'-dioxidobifenyl-4,4'- diyldiazo)bis(6-(4-(3- (dietylamino)propylamino)-6-(-3- (dietylammonio)propylamino)-1,3,5- triazin-2-ylamino)-3-sulfonato-1- naftolato))dikoppar(ii)acetatlaktat dinatrium-7-[4-klor-6-(n-etyl-o- toluidino)-1,3,5-triazin-2-ylamino]- 4-hydroxi-3-(4-metoxi-2- sulfonatofenylazo)2-naftalensulfonat

39 signalords natrium-3-(2-acetamido-4-(4-(2- hydroxibutoxi)fenylazo)fenylazo)ben sensulfonat tetranatrium[7-(2,5-dihydroxi-ko2-7-sulfonato-6-[4-(2,5,6- triklorpyrimidin-4- ylamino)fenylazo]-(n1,n7-n)1- naftylazo)-8-hydroxi-ko8-naftalen- 1,3,5-trisulfonato(6)]kuprat(II) reaktionsblandning av: pentanatriumbis(1-(3(eller 5)-(4- anilino-3-sulfonatofenylazo)-4- hydroxi-2-oxidofenylazo)-6-nitro-4- sulfonato-2-naftolato)ferrat(1-); pentanatrium[(1-(3-(4-anilino-3- sulfonatofenylazo)-4-hydroxi-2- oxidofenylazo)-6-nitro-4-sulfonato- 2-naftolato)-(5-(4-anilino-3- sulfonatofenylazo)-4-hydroxi-2- oxidofenylazo)-6-nitro-4-sulfonato- 2-naftolato]ferrat(1-) reaktionsblandning av: 2-[N-etyl-4- [(5,6-diklorbensotiazol-2-yl)azo]-mtoludino]etylacetat; 2-[N-etyl-4-[(6,7-diklorbensotiazol- 2-yl)azo]-m-toludino]etylacetat (1:1) STOT RE 1 H372 ** H372 ** 401

40 signalords reaktionsblandning av: 3-cyano-5-(2- cyano-4-nitrofenylazo)-2-(2- hydroxietylamino)-4-metyl-6-[3-(2- fenoxietoxi)propylamino]pyridin; 3- cyano-5-(2-cyano-4-nitrofenylazo)- 6-(2-hydroxietylamino)-4-metyl-2- [3-(2- fenoxietoxi)propylamino]pyridin; 3-cyano-5-(2-cyano-4- nitrofenylazo)-2-amino-4-metyl-6- [3-(3- hydroxipropoxi)propylamino]pyridin ; 3-cyano-5-(2-cyano-4- nitrofenylazo)-6-amino-4-metyl-2- [3-(3- metoxipropoxi)propylamino]pyridin X monolitium-5-[[2,4-dihydroxi-5-[(2- hydroxi-3,5- dinitrofenyl)azo]fenyl]azo]-2- naftalensulfonat], järnkomplex, monohydrat reaktionsblandning av: 3-((5-cyano- 1,6-dihydro-1,4-dimetyl-2-hydroxyl- 6-oxo-3-pyridinyl)azo)-bensoyloxi- 2-fenoxietan; 3-((5-cyano-1,6-dihydro-1,4- dimetyl-2-hydroxi-6-oxo-3- pyridinyl)azo)-bensoyloxi-2-etyloxi- 2-(etylfenol) Aquatic Chronic 4 H413 H

41 signalords reaktionsblandning av: trilitium-4- amino-3-((4-((4-((2-amino-4- hydroxifenyl)azo)fenyl)amino)-3- sulfofenyl)azo)-5-hydroxi-6- (fenylazo)naftalen-2,7-disulfonat; trilitium-4-amino-3-((4-((4-((4- amino-2- hydroxifenyl)azo)fenyl)amino)-3- sulfofenyl)azo)-5-hydroxi-6- (fenylazo)naftalen-2,7-disulfonat ((4-(etyl-(2-hydroxietyl)amino)-2- metylfenyl)azo)-6-metoxi-3-metylbensotiazoliummetylsulfat ,5-dibutoxi-4-(morfolin-4- yl)bensendiazonium-4- metylbensensulfonat Self-react. C H242 GHS02 H242 T natrium (1,0-1,95)/litium (0,051) 5- ((5-((5-klor-6-fluor-pyrimidin-4- yl)amino)-2-sulfonatofenyl)azo)-1,2- dihydro-6-hydroxi-1,4-dimetyl-2- oxo-3-pyridinmetylsulfonat tert-(dodecyl/tetradecyl)- ammoniumbis(3-(4-((5-(1,1- dimetylpropyl)-2-hydroxi-3- nitrofenyl)azo)-3-metyl-5-hydroxi- (1H)-pyrazol-1- yl)bensensulfonamidato)kromat

42 signalords natrium-2-(4-(4-fluor-6-(2-sulfo- etylamino)-[1,3,5]triazin-2-ylamino)- 2-ureidofenylazo)-5-(4- sulfofenylazo)bensen-1-sulfonat reaktionsblandning av: 2-[2- acetylamino-4-[n,n-bis[2-etoxi- karbonyloxi)etyl]amino]fenylazo]- 5,6-diklor-1,3-bensotiazol; 2-[2-acetylamino-4-[N,N-bis[2-etoxi- karbonyloxi)etyl]amino]fenylazo]- 6,7-diklor-1,3-bensotriazol (1:1) Aquatic Chronic 4 H413 H hexanatrium-1,1'-[(1-amino-8- hydroxi-3,6-disulfonat-2,7- naftalendiyl)bis(azo(4-sulfonat-1,3- fenyl)imino[6[(4-klor-3- sulfonatofenyl)amino]-1,3,5-triazin- 2,4-diyl]]]bis[3- karboxipyridinium]dihydroxid metyl-n-[3-acetylamino)-4-(2- cyano-4-nitrofenylazo)fenyl]-n-[(1- metoxi)acetyl]glycinat

43 signalords X reaktionsblandning av järnkomplex av: 1,3-dihydroxi-4-[(5- fenylaminosulfonyl)-2- hydroxifenylazo]-n-(5-aminosulfonyl-2-hydroxifenylazo)bensen och: 1,3-dihydroxi-4-[(5- fenylaminosulfonyl)-2- hydroxifenylazo]-n-[4-(4-nitro-2- sulfofenylamino)fenylazo]bensen (n = 2,5,6) tetrakis(tetrametylammonium)-3,3'- (6-(2-hydroxietylamino)-1,3,5- triazin-2,4-diylbisimino(2-metyl-4,1- fenylenazo))bisnaftalen-1,5- disulfonat Aquatic Chronic (metylenbis(4,1-fenylenazo(1-(3- (dimetylamino)propyl)-1,2-dihydro- 6-hydroxi-4-metyl-2-oxopyridin-5,3- diyl)))-1,1'- dipyridiniumdikloriddihydroklorid Carc. 1B kaliumnatrium-3,3'-(3(eller 4)-metyl- 1,2-fenylenbis(imino(6-klor)-1,3,5- triazin-4,2-diylimino(2-acetamido-5- metoxi)-4,1-fenylenazo)dinaftalen- 1,5-disulfonat X 2'-(4-klor-3-cyano-5-formyl-2- tienyl)azo-5'-dietylaminoacetanilid

44 signalords reaktionsprodukt av: C.I. Leuco Sulfur Black 1 och reaktionsblandning av: dinatrium-4- {4-[8-amino-1-hydroxi-7-(4- sulfamoylfenylazo)-3,6-disulfonato- 2- naftylazo{]fenylsulfonylamino[}ben sendiazoniumklorid;dinatrium-4-{4- [2,6-dihydroxi-3-(8-hydroxi-3,6- disulfonato-1- naftylazo)fenylazo]fenylsulfonylami no}bensen-diazoniumklorid trinatrium(1-(3-karboxylato-2-oxido- 5-sulfonatofenylazo)-5-hydroxi-7- sulfonatonaftalen-2-amido)nickel(ii)

45 signalords reaktionsblandning av: trinatrium- (2,4(eller 2,6 eller 4,6)-bis(3,5- dinitro-2-oxidofenylazo)-5- hydroxifenolato)(2(eller 4 eller 6)- (3,5-dinitro-2-oxidofenylazo)5- hydroxi-4(eller 2 eller 6)-(4-(4-nitro- 2- sulfonatoanilino)fenylazo)fenolato)fe rrat(1-); trinatriumbis(2,4(eller 2,6 eller 4,6)-bis(3,5-dinitro-2- oxidofenylazo)-5- hydroxifenolato)ferrat(1-); trinatrium(2,4(eller 2,6 eller 4,6)- bis(3,5-dinitro-2-oxidofenylazo)-5- hydroxifenolato)(2(eller 4 eller 6)- (3,5-dinitro-2-oxidofenylazo)-5- hydroxi-4(eller 2 eller 6)-(4-nitro-2- sulfonatofenylazo)fenolato)ferrat(1- ); trinatrium(2,4(eller 2,6 eller 4,6)- bis(3,5-dinitro-2-oxidofenylazo)-5- hydroxifenolato)(2(eller 4 eller 6)- (3,5-dinitro-2-oxidofenylazo)-5- hydroxi-4(eller 2 eller 6)-(3- sulfonatofenylazo)fenolato)ferrat(1- ); dinatrium-3,3'-(2,4-dihydroxi- 1,3(eller 1,5 eller 3,5)- fenylendiazo)dibensensulfonat natrium-4-(4-klor-6-(n-etylanilino)- 1,3,5-triazin-2-ylamino)-2-(1-(2- klorfenyl)-5-hydroxi-3-metyl-1hpyrazol-4-ylazo)bensensulfonat hexanatrium-4,4'-dihydroxi-3,3'- bis[2-sulfonato-4-(4- sulfonatofenylazo)fenylazo]-7,7'[p- fenylenbis[imino(6-klor-1,3,5- triazin-4,2-diyl)imino]]dinaftalen-2- sulfonat

46 signalords kaliumnatrium-4-(4-klor-6-(3,6- disulfonato-7-(5,8-disulfonato- naftalen-2-ylazo)-8-hydroxi-naftalen-1- ylamino)-1,3,5-triazin-2-ylamino)-5- hydroxi-6-(4-(2-sulfatoetansulfonyl)- fenylazo)-naftalen-1,7-disulfonat dinatrium-5-((4-((4-klor-3- sulfonatofenyl)azo)-1-naftyl)azo)-8- (fenylamino)-1-naftalensulfonat reaktionsprodukter av: koppar(ii)sulfat och tetranatrium-2,4-bis[6-(2-metoxi- 5-sulfonatofenylazo)-5-hydroxi-7- sulfonato-2-naftylamino]-6-(2- hydroxietylamino)-1,3,5-triazin (2:1) tetra-natrium/litium-4,4'-bis-(8-amino- 3,6-disulfonato-1-naftol-2-ylazo)-3- metylazobensen dinatrium-2-[[4-(2- kloretylsulfonyl)fenyl]-[(2-hydroxi-5- sulfo-3-[3-[2-(2- (sulfooxi)etylsulfonyl)etylazo]-4- sulfobensoato(3-)kuprat(1-)

47 signalords X tetranatrium-4-hydroxi-5-[4-[3-(2- sulfatoetansulfonyl)fenylamino]-6- morfolin-4-yl-1,3,5-triazin-2-ylamino]- 3-(1-sulfonatonaftalen-2- ylazo)naftalen-2,7-disulfonat litiumnatrium(2-(((5-((2,5- diklorfenyl)azo)-2- hydroxifenyl)metylen)amino)bensoato( 2-))(2-((4,5-dihydro-3-metyl-5-oxo-1- fenyl-1h-pyrazol-4-yl)azo)-5- sulfobensoato(3-))kromat(2-) litiumnatrium(4-((5-klor-2- hydroxifenyl)azo)-2,4-dihydro-5- metyl-3h-pyrazol-3-onato(2-))(3-((4,5- dihydro-3-metyl-1-(4-metylfenyl)-5- oxo-1h-pyrazol-4-yl)azo)-4-hydroxi-5- nitrobensensulfonato(3-))kromat(2-) trilitiumbis(4-((4-(dietylamino)-2- hydroxifenyl)azo)-3-hydroxi-1- naftalensulfonato(-3-))kromat(3-)

48 signalords reaktionsblandning av: trinatrium- 5{4-klor-6-[2-(2,6-diklor-5- cyanopyrimidin-4-ylamino)- propylamino]-1,3,5-triazin-2- ylamino}-4-hydroxi-3-(1- sulfonatonaftalen-2-ylazo)-naftalen- 2,7-disulfonat; trinatrium-5-{4-klor-6-[2-(2,6- diklor-5-cyanopyrimidin-4-ylamino)- 1-metyl-etylamino]-1,3,5-triazin-2- ylamino}-4-hydroxi-3-(1- sulfonatonaftalen-2-ylazo)-naftalen- 2,7-disulfonat; trinatrium-5-{4-klor-6-[2-(4,6- diklor-5-cyanopyrimidin-2-ylamino)- propylamino]-1,3,5-triazin-2- ylamino}-4-hydroxi-3-(1- sulfonatonaftalen-2-ylazo)-naftalen- 2,7-disulfonat; trinatrium-5-{4-klor-6-[2-(4,6- diklor-5-cyanopyrimidin-2-ylamino)- 1-metyl-etylamino]-1,3,5-triazin-2- ylamino}-4-hydroxi-3-(1- sulfonatonaftalen-2-ylazo)-naftalen- 2,7-disulfonat ,3-bis{6-fluor-4-[1,5-disulfo-4-(3- aminokarbonyl-1-etyl-6-hydroxi-4- metylpyrid-2-on-5-ylazo)-fenyl-2- ylamino]-1,3,5-triazin-2- ylamino}propanlitium-, natriumsalt

49 signalords natrium-1,2-bis[4-[4-{4-(4- sulfofenylazo)-2-sulfofenylazo}-2- ureido-fenyl-amino]-6-fluor-1,3,5- triazin-2-ylamino]-propan, natriumsalt tetranatrium-4-[4-klor-6-(4-metyl-2- sulfofenylamino)-1,3,5-triazin-2- ylamino]-6-(4,5-dimetyl-2- sulfofenylazo)-5-hydroxinaftalen- 2,7-disulfonat {4-[5-amino-2-[4-(2- sulfoxietylsulfonyl)fenylazo]-4- sulfo-fenylamino]-6-klor-1,3,5- triazin-2-ylamino}-4-hydroxi-3-(1- sulfo-naftalen-2-ylazo)-naftalen-2,7- disulfonsyra natriumsalt huvudbeståndsdel 6 (isomer): asym. 1:2 Cr(III)-komplex av: A: 3- hydroxi-4-(2-hydroxinaftalen-1- ylazo)naftalen-1-sulfonsyra, Na-salt och B: 1-[2-hydroxi-5-(4- metoxifenylazo)fenylazo]naftalen-2- ol; huvudbeståndsdel 8 (isomer): asym. 1:2 Cr-komplex av: A: 3-hydroxi-4-(2-hydroxinaftalen-1- ylazo)naftalen-1-sulfonsyra, Na-salt och B: 1-[2-hydroxi-5-(4- metoxifenylazo)fenylazo]-naftalen- 2-ol

50 signalords hexanatrium(di[n-(3-(4-[5-(5-amino- 3-metyl-1-fenylpyrazol-4-ylazo)-2,4- disulfoanilino]-6-klor-1,3,5-triazin- 2- ylamino)fenyl)sulfamoyl](disulfo)fta locyaninato)nickel X 3-(2,4-bis(4-((5-(4,6-bis(2- aminopropylamino)-1,3,5-triazin-2- ylamino)-4-hydroxi-2,7- disulfonaftalen-3- yl)azo)fenylamino)-1,3,5-triazin-6- ylamino)propyldietylammoniumlakta t reaktionsblandning av: pentanatrium- 5-amino-3-(5-{4-klor-6-[4-(2- sulfoxietoxisulfonato)fenylamino]- 1,3,5-triazin-2-ylamino}-2- sulfonatofenylazo)-6-[5-(2,3- dibrompropionylamino)-2- sulfonatofenylazo]-4- hydroxinaftalen-2,7-disulfonat; pentanatrium-5-amino-6-[5-(2- bromakryloylamino)-2- sulfonatofenylazo]-3-(5-{4-klor-6- [4-(2- sulfoxietoxisulfonato)fenylamino]- 1,3,5-triazin-2-ylamino}-2- sulfonatofenylazo)-4- hydroxinaftalen-2,7-disulfonat; tetranatrium-5-amino-3-[5-{4-klor-6- [4-(vinylsulfonyl)fenylamino]-1,3,5- triazin-2-ylamino}-2- sulfonatofenylazo]-6-[5-(2,3- dibrompropionylamino)-2- sulfonatofenylazo]-4- hydroxinaftalen-2,7-disulfonat

51 signalords reaktionsblandning av: dinatrium-6- [3-karboxi-4,5-dihydro-5-oxo-4- sulfonatofenyl)pyrazolin-4-ylazo]-3- [2-oxido-4-(etensulfonyl)-5- metoxifenylazo]-4-oxidonaftalen-2- sulfonat, koppar(ii)komplex; dinatrium-6-[3-karboxi-4,5-dihydro- 5-oxo-4-sulfonatofenyl)pyrazolin-4- ylazo]-3-[2-oxido-4-(2- hydroxietylsulfonyl)-5- metoxifenylazo]-4-oxidonaftalen-2- sulfonat, koppar(ii)komplex ,6-bis-(2-(4-(4-amino-fenylamino)- fenylazo)-1,3-dimetyl-3h- imidazolium)-4-dimetylamino-1,3,5- triazin, diklorid pentanatrium-4-amino-6-(5-(4-(2- etyl-fenylamino)-6-(2- sulfatoetansulfonyl)-1,3,5-triazin-2- ylamino)-2-sulfonatofenylazo)-5- hydroxi-3-(4-(2- sulfatoetansulfonyl)fenylazo)naftalen -2,7-disulfonat G N,N'-bis{6-klor-4-[6-(4- vinylsulfonylfenylazo)-2,7- disulfonsyra-5-hydroxinaft-4- ylamino]-1,3,5-triazin-2-yl}n-(2- hydroxietyl)etan-1,2-diamin, natriumsalt

52 signalords reaktionsblandning av: 5-[(4-[(7- amino-1-hydroxi-3-sulfo-2- naftyl)azo]-2,5-dietoxifenyl)azo]-2- [(3-fosfonofenyl)azo]bensoesyra; 5-[(4-[(7-amino-1-hydroxi-3-sulfo-2- naftyl)azo]-2,5-dietoxifenyl)azo]-3- [(3-fosfonofenyl)azo]bensoesyra Expl. 1.3 **** Repr. 2 H203 H361f *** GHS01 H203 H361f *** tetraammonium-2-[6-[7-(2- karboxylatofenylazo)-8-hydroxi-3,6- disulfonato-1-naftylamino]-4- hydroxi-1,3,5-triazin-2- ylamino]bensoat Eye Irrit [2-hydroxi-3-(2- klorfenyl)karbamoyl-1-naftylazo]-7- [2-hydroxi-3-(3- metylfenyl)karbamoyl-1- naftylazo]fluoren-9-on Repr. 1B Aquatic Chronic 4 H360D *** H413 H360D *** H pentanatriumbis{7-[4-(1-butyl-5- cyano-1,2-dihydro-2-hydroxi-4- metyl-6-oxo-3- pyridylazo)fenylsulfonylamino]-5'- nitro-3,3'-disulfonatonaftalen-2- azobensen-1,2'-diolato}kromat(iii)

53 signalords product-by-process järnkomplex av azofärgämnen som framställs genom koppling av en blandning av diazoterad 2-amino-1- hydroxibensen-4-sulfanilid och 2- amino-1-hydroxibensen-4- sulfonamid med resorcin, den erhållna blandningen genomgår därefter en andra kopplingsreaktion med en blandning av diazoterad 3- aminobensen-1-sulfonsyra (metanilsyra) och 4'-amino-4-nitro- 1,1'-difenylamin-2-sulfonsyra och metallisering med järn(iii)klorid, natriumsalt X trinatrium-2-{α[2-hydroxi-3-[4-klor- 6-[4-(2,3-dibrompropionylamino)-2- sulfonatofenylamino]-1,3,5-triazin-2- ylamino]-5-sulfonatofenylazo]- bensylidenhydrazino}-4- sulfonatobensoat, kopparkomplex reaktionsprodukt av: 2-[[4-amino-2- ureidofenylazo]-5-[(2- (sulfooxi)etyl)sulfonyl]]bensensulfon syra med 2,4,6-trifluorpyrimidin och partiell hydrolys till motsvarande vinylsulfonylderivat, blandat kalium/natriumsalt {4-(2-ammoniopropylamino)-6-[4- hydroxi-3-(5-metyl-2-metoxi-4- sulfamoylfenylazo)-2-sulfonatonaft- 7-ylamino]-1,3,5-triazin-2-ylamino}- 2-aminopropylformiat Repr. 2 H361f *** H361f *** 415

54 signalords tert-butyl-7-klor-3-tridecyl-7,7a- dihydro-1h-pyrazolo[5,1-c]-1,2,4- triazol Aquatic Chronic 4 H413 H (4-aminofenyl)-6-tert-butyl-1Hpyrazolo[1,5-b][1,2,4]triazol reaktionsprodukt av: C.I. Leuco Sulfur Black 1 med (3-klor-2- hydroxipropyl)trimetylammoniumkl orid azafenidin (ISO); 2-(2,4-diklor-5-prop-2- ynyloxifenyl)-5,6,7,8-tetrahydro- 1,2,4-triazolo[4,3-a]pyridin-3(2H)- on Repr. 1B H360Df H360Df M = (4-[4-[4-(3,5- dikarboxifenylazo)fenylamino]-6- morfolin-4-yl-1,3,5-triazin-2- ylamino]fenylazo)isoftalsyra, blandat mononatrium- och diammoniumsalt

55 signalords product-by-process -definition polyazofärgämne som framställs genom koppling av 4-[4-(1-amino-8- hydroxi-3,6-disulfo-2- naftylazo)fenylsulfonylamino]bensen diazonium med reaktionsblandning av 4-karboxibensendiazonium och difenylamin-3-sulfo-4,4'- bisdiazonium, och ytterligare koppling av de erhållna föreningarna med reaktionsblandning av naft-2-ol och 3-aminofenol, natriumsalter; natriumklorid reaktionsblandning av: trinatrium-2- (2-[α-(2-karboxylato-κ-O-4- sulfonatofenylazo)bensyliden]hydraz ino-κ-n')-6-(2,6-difluorpyrimidin-4- ylamino)-4- sulfonatofenolatokuprat(ii); trinatrium-2-(2-[α-(2-karboxylato-κ- O-4- sulfonatofenylazo)bensyliden]hydraz ino-κ-n')-6-(4,6-difluorpyrimidin-2- ylamino)-4- sulfonatofenolatokuprat(ii)

56 signalords reaktionsblandning av: 7-amino-3,8- bis-[4-(2- sulfoxietylsulfonyl)fenylazo]-4- hydroxinaftalen-2-sulfonsyra, Na/Ksalt; 7-amino-3-[4-(2- sulfoxietylsulfonyl)fenylazo]-4- hydroxi-8-[4-(2-sulfoxietylsulfonyl)- 2-sulfofenylazo]naftalen-2- sulfonsyra, Na/K-salt; 7-amino-8-[4- (2-sulfoxietylsulfonyl)fenylazo]-4- hydroxi-3-[4-(2-sulfoxietylsulfonyl)- 2-sulfofenylazo]naftalen-2- sulfonsyra, Na/K-salt; 7-amino-3,8- bis-[4-(2-sulfoxietylsulfonyl)-2- sulfofenylazo]-4-hydroxinaftalen-2- sulfonsyra, Na/K-salt X reaktionsblandning av: tetranatrium- 3-(1,5-disulfonatonaftalen-2-ylazo)- 4-hydroxi-7-{4-klor-6-[4-(2- sulfoxietylsulfonyl)fenylamino]- 1,3,5-triazin-2-ylamino}naftalen-2- sulfonat; 3-(2,5-disulfofenylazo)-4-hydroxi-7- {4-klor-6-[4-(2- sulfoxietylsulfonyl)fenylamino]- 1,3,5-triazin-2-ylamino}naftalen-2- sulfonsyra, natriumsalt

57 signalords reaktionsblandning av: pentanatrium- 3-(4-(4-(7-(2,4-diamino-5-sulfonato- 3-(4-sulfonatofenylazo)fenylazo)-1- hydroxi-3-sulfonatonaftalen-2- ylazo)-2- sulfonatofenylamino)fenylazo)-4- hydroxi-6-(2-oxo-1- fenylkarbamoylpropylazo)naftalen- 2-sulfonat; pentanatrium-6-((2,4- diamino-5-sulfonatofenyl)azo)-3-((4- ((4-((7-((2,4-diamino-5- sulfonatofenyl)azo)-1-hydroxi-3- sulfonatonaftalen-2- yl)azo)fenyl)amino)-2- sulfonatofenyl)azo)-4- hydroxinaftalen-2-sulfonat; pentanatrium-6-((2,4-diamino-5- sulfonato-3-((4- sulfonatofenyl)azo)fenyl)azo)-3-((4- ((4-((1,7-dihydroxi-3- sulfonatonaftalen-2-yl)azo)-2- sulfonatofenyl)amino)fenyl)azo)-4- hydroxinaftalen-2-sulfonat; hexanatrium-6-((2,4-diamino-5- sulfonatofenyl)azo)-3-((4-((4-((7- ((2,4-diamino-5-sulfonato-3-((4- sulfonatofenyl)azo)fenyl)azo)-1- hydroxi-3-sulfonatonaftalen-2- yl)azo)-2- sulfonatofenyl)amino)fenyl)azo)-4- hydroxinaftalen-2-sulfonat natrium-, kalium-, litium-5-amino- 3,6-bis(5-(4-klor-6-(metyl-(2- metylaminoacetyl)amino)-1,3,5- triazin-2-ylamino)-2- sulfonatofenylazo)-4- hydroxinaftalen-2,7-disulfonat

58 signalords reaktionsblandning av: 2-(3-(2,6- diklor-4-nitrofenylazo)karbazol-9- yl)etanol; 2-(2-(3-(2,6-diklor-4-nitrofenylazo)- karbazol-9-yl)etoxi)etanol; 3-(2,6-diklor-4- nitrofenylazo)karbazol (2-kloracetoxi)etyl-3-((4-(2,5- diklor-4-fluorsulfonylfenylazo)-3- metylfenyl)etylamino)propionat tetralitium-2-[6-[7-[2- (karboxylato)fenylazo]-8-hydroxi- 3,6-disulfonato-1-naftylamino]-4- hydroxi-1,3,5-triazin-2- ylamino]bensoat Eye Irrit krysoidin; 4-(fenylazo)bensen-1,3-diamin Muta. 2 Skin Irrit. 2 H341 H

59 signalords krysoidinmonohydroklorid; 4-fenylazofenylen-1,3- diaminmonohydroklorid; [1] krysoidinmonoacetat; 4-(fenylazo)bensen-1,3- diaminmonoacetat; [2] krysoidinacetat; 4-(fenylazo)bensen-1,3- diaminacetat; [3] krysoidin-p-dodecylbensensulfonat; dodecylbensensulfonsyra, förening med 4-(fenylazo)bensen-1,3-diamin (1:1); [4] krysoidindihydroklorid; 4-(fenylazo)bensen-1,3- diamindihydroklorid; [5] krysoidinsulfat; bis[4-(fenylazo)bensen-1,3- diamin]sulfat [6] [1] [2] [3] [4] [5] [6] [1] [2] [3] [4] [5] [6] Muta. 2 Skin Irrit. 2 H341 H krysoidin-c alkylderivat; bensensulfonsyra, mono-c alkylderivat, föreningar med 4-(fenylazo)-1,3-bensendiamin; [1] krysoidinförening med dibutylnaftalensulfonsyra; dibutylnaftalensulfonsyra, förening med 4-(fenylazo)bensen-1,3-diamin (1:1) [2] [1] [2] [1] [2] Muta. 2 Skin Irrit. 2 H341 H trinatrium-5-bensamido-4-hydroxi-3- (4-metyl-2- sulfonatofenylazo)naftalen-2,7- disulfonat

60 signalords ,4'-oxibis(bensensulfonylazid) Expl. 1.1**** H201 H373** GHS01 H201 H373** X triammonium 4-[4-[7-(4- karboxylatoanilino)-1-hydroxi-3- sulfonato-2-naftylazo]-2,5- dimetoxifenylazo]bensoat Repr. 2 H361f*** H373** H361f*** H373** bensensulfonsyra, 3,3'- (metylenbis((dihydroxifenylen)azo)) bis-, kaliumnatriumsalt; kaliumnatrium-3-[(e)-(6{3,4- dihydroxi-2-}(z)-(3- sulfonatofenyl)diazenyl]bensyl}-2,3- dihydroxifenyl)diazenyl]bensensulfo nat Eye Irrit reaktionsprodukt av: 2,3,4,2', 3', 4'-hexahydroxi-5,5'- diacetyldifenylmetan och 6-diazo- 5,6-dihydro-5-oxo-1- naftalensulfonylklorid och 3-diazo- 3,4-dihydro-6-metoxi-4-oxo-1- naftalensulfonylklorid **** Aquatic Chronic 4 **** H413 **** **** H dinatrium-4-amino-6-((4-((4-(2,4- diaminofenyl)azo)fenylsulfamoyl)fe nyl)azo)-5-hydroxi-3-((4- nitrofenyl)azo)naftalen-2,7- disulfonat